The chemistry of binuclear palladium(II) and platinum(II) complexes |
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| Authors: | Vimal K. Jain Leela Jain |
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| Affiliation: | a Novel Materials and Structural Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India
b Department of Chemistry, VES College, Chembur, Mumbai 400076, India |
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| Abstract: | The chemistry of binuclear palladium(II) and platinum(II) complexes has been reviewed. This review deals with complexes derived from various classes of ligands and covers various aspects, viz. synthesis, spectroscopic and structural features and chemical reactivity, of these complexes. Applications of these complexes are briefly described in the respected sections. |
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| Keywords: | dmpm, bis(dimethylphosphino)methane dppm, bis(diphenylphosphino)methane depm, Et2PCH2PEt2 dipm, Pr2iCH2PPr2i dppe, 1,2-bis(diphenylphosphino)ethane dppp, 1,3-bis(diphenylphosphino)propane dppen, cis-Ph2PCH![]() 0" alt=" double bond length as m-dash" src=" http://cdn.els-cdn.com/sd/entities/dbnd" class=" glyphImg" >CHPPh2 dppa, 1,2-bis(diphenylphosphino)acetylene dpm, Ph2PCH(Me)PPh2 dpam, 1,2-bis(diphenylarsino)ethane dppam, Ph2PCH2AsPh2 dpsm, Ph2SbCH2SbPh2 dppet, Ph2PCH2CH2S- pz, pyrazolate dmpz, 3,5-dimethylpyrazolate tmpz, 3,4,5-trimethylpyrazolate N3C2H2, 1,2,3-triazolate az, azaindolate dpf, diphenylformidinate gua, guanidine COD, 1,5-cycloocadiene nbd, norbornadiene prolophos, >![]() 65" border=" 0" align=" middle" width=" 103" style=" vertical-align: bottom " alt=" Image" title=" Image" src=" http://ars.els-cdn.com/content/image/1-s2.0-S0010854505001554-fx1.gif" > butaphos, >![]() 62" border=" 0" align=" middle" width=" 81" style=" vertical-align: bottom " alt=" Image" title=" Image" src=" http://ars.els-cdn.com/content/image/1-s2.0-S0010854505001554-fx2.gif" > biim, >![]() 97" border=" 0" align=" middle" width=" 62" style=" vertical-align: bottom " alt=" Image" title=" Image" src=" http://ars.els-cdn.com/content/image/1-s2.0-S0010854505001554-fx3.gif" > bipym, >![]() 32" border=" 0" align=" middle" width=" 64" style=" vertical-align: bottom " alt=" Image" title=" Image" src=" http://ars.els-cdn.com/content/image/1-s2.0-S0010854505001554-fx4.gif" > bptz, >![]() 40" border=" 0" align=" middle" width=" 146" style=" vertical-align: bottom " alt=" Image" title=" Image" src=" http://ars.els-cdn.com/content/image/1-s2.0-S0010854505001554-fx5.gif" > bipy, 2,2&prime -bipyrdine phen, 1,10-phenanthroline trpy, 2,2&prime ,2&Prime -terpyridine py, pyridine tmeda, Me2NCH2CH2NMe2 en, ethylenediamine GSH, glutathione Haccys, N-acetylcysteine pytH, 2-mercaptopyridine dppf, (Ph2PC5H4)2Fe np, N(CH2CH2PPh2)3 tht, tetrahydrothiophene Mes, 2,4,6-Me3C6H2 c-Hx, cyclohexyl Th, 2-thineyl acacH, acetylcetone bzacH, benzoylacetone OxH, 8-hydroxyquinoline c-Hx3P, tricyclohexylphosphine Honp, >![]() 57" border=" 0" align=" middle" width=" 89" style=" vertical-align: bottom " alt=" Image" title=" Image" src=" http://ars.els-cdn.com/content/image/1-s2.0-S0010854505001554-fx6.gif" > Hmonp, >![]() 54" border=" 0" align=" middle" width=" 116" style=" vertical-align: bottom " alt=" Image" title=" Image" src=" http://ars.els-cdn.com/content/image/1-s2.0-S0010854505001554-fx7.gif" > Pap, cyclometallated azobenzene |
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