Acylpyrazolone ligands: Synthesis, structures, metal coordination chemistry and applications |
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| Authors: | Fabio Marchetti Claudio Pettinari Riccardo Pettinari |
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| Affiliation: | Dipartimento di Scienze Chimiche, Università degli Studi di Camerino, via S. Agostino 1, 62032 Camerino (MC), Italy |
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| Abstract: | This review summarizes the literature on 4-acyl-5-pyrazolone ligands, their synthesis, characterization and coordination chemistry toward main group, transition, lanthanide and actinide metals and relevant applications of their metal complexes. |
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| Keywords: | acacH, 2,4-pentanedione bipy, 2,2&prime -bipyridine Bnim, 1-benzylimidazole Bn, benzyl Bu, butyl iBu, iso-butyl tBu, tert-butyl bzpy, 2-benzoylpyridine cod, 1,5-cyclooctadiene coe, cyclooctene cot, cyclooctatetraene Cp, cyclopentadienyl cupr, 2,9-dimethyl-1,10-phenanthroline Cy, cyclohexyl dbzmH, dibenzoylmethane Dd, dodecanoyl diglyme, 2,5,8-trioxanonane dmaeH, N,N-dimethylaminoethanol dmf, dimethylformamide dmso, dimethylsulphoxide diphen, 4,7-dimethyl-1,10-phenanthroline dppb, bis(diphenylphosphino)butane dppe, bis(diphenylphosphino)ethane dppf, 4,4&prime -bis(diphenylphosphino)ferrocene dppm, bis(diphenylphosphino)methane dppof, 4,4&prime -bis(diphenylphosphinooxide)ferrocene dppp, bis(diphenylphosphino)propane en, ethylene Et, ethyl etCp, ethylene-cyclopentadienyl fur, furyl H2C(tmpz)2, bis(3,4,5-trimethylpyrazol-l-yl)methane) haphH, 2-hydroxyacetophenone (Hd, heptadecyl He, hexyl hex, 1,5-hexadiene Hmimt, 1-methylimidazolin-2-thione Hp, heptyl imH, imidazole Me, methyl Meim, 1-methylimidazole 2-MeimH, 2-methylimidazole moeH, 2-methoxyethanol nbd, 2,5-norbornadiene OAc, CH3COO Oc, octyl pephen, 4,7-dipheyl-1,10-phenanthroline Pd, pentadecyl nPe, neo-pentyl Ph, phenyl phen, 1,10-phenanthroline phencarz, 1-ethyl-2-(N-ethyl-carbazole-4-yl)imidazo[4,5-f]-1,10-phenanthroline pmdien, N,N,N&prime ,N&Prime ,N&Prime -pentamethyl-diethylenetriamine Pr, propyl iPr, iso-propyl py, pyridyl pypr, 2,3-bis(2-pyridil)pyrazine pzH, pyrazole sm, succinimide terpy, terpyridine tetraglyme, 2,5,8,11,14-pentaoxapentadecane tfb, tetrafluorobenzobarrelene thf, tetrahydrofurane thi, thienyl tmeda, N,N,N&prime ,N&prime -tetramethylethylenediamine tmpzH, 3,4,5-trimethylpyrazole triglyme, 2,5,8,11-tetraoxadodecane trime, N,N,N&prime -trimethylethylenediamine tppo, triphenylphosphine oxide ttaH, thenoyltrifluoroacetone Vy, vinyl Xd, hexadecyl |
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