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Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XV. Synthesis of bis-4,5-(phenylsulfanyl)phthalonitrile,octakis-4,5-(phenylsulfanyl)phthalocyanines,and their sulfo and alkylsulfamoyl derivatives
Authors:S A Znoiko  E S Golovashova  O V Potekhina  D B Berezin  M A Serova  V E Maizlish  G P Shaposhnikov
Institution:1.Research Institute of Macroheterocyclic Chemistry,Ivanovo State University of Chemical Technology,Ivanovo,Russia
Abstract:Novel water- and organic-soluble derivatives of octakis-4,5-(sulfanylphenyl)phthalocyanine and its magnesium and aluminum complexes were synthesized starting from 4,5-bis(phenylsulfanyl)phthalonitrile obtained by nucleophilic substitution of the bromine and nitro group in 4-bromo-5-nitrophthalonitrile. Spectral and luminescence characteristics of the newly synthesized compounds were studied.
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