Nucleophilic substitution in 4-bromo-5-nitrophthalodinitrile: XV. Synthesis of bis-4,5-(phenylsulfanyl)phthalonitrile,octakis-4,5-(phenylsulfanyl)phthalocyanines,and their sulfo and alkylsulfamoyl derivatives |
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Authors: | S A Znoiko E S Golovashova O V Potekhina D B Berezin M A Serova V E Maizlish G P Shaposhnikov |
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Institution: | 1.Research Institute of Macroheterocyclic Chemistry,Ivanovo State University of Chemical Technology,Ivanovo,Russia |
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Abstract: | Novel water- and organic-soluble derivatives of octakis-4,5-(sulfanylphenyl)phthalocyanine and its magnesium and aluminum complexes were synthesized starting from 4,5-bis(phenylsulfanyl)phthalonitrile obtained by nucleophilic substitution of the bromine and nitro group in 4-bromo-5-nitrophthalonitrile. Spectral and luminescence characteristics of the newly synthesized compounds were studied. |
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