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Ferric nitrate-promoted oxidative esterification of toluene with N-hydroxyphthalimide: Synthesis of N-hydroxyimide esters |
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| Authors: | Pingping Li Jian Sun Xiaohe Xu Zhisheng Mi Yuyan Lin Jingya Cheng Renren Bai Yuanyuan Xie |
| Institution: | 1. College of Pharmaceutical sciences, Zhejiang University of Technology, Hangzhou, PR China;2. Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals, Zhejiang University of Technology, Hangzhou, PR China |
| Abstract: | A ferric nitrate-promoted cross-dehydrogenative coupling reaction of N-hydroxyphthalimide (NHPI) with toluene derivatives is reported. The reaction proceeded smoothly using molecular oxygen as an oxidant, providing an efficient method for the synthesis of N-hydroxyimide esters. Furthermore, a plausible mechanism was proposed. |
| Keywords: | Cross-dehydrogenative coupling Toluene derivatives Corresponding author at: College of Pharmaceutical sciences Zhejiang University of Technology Hangzhou PR China Collaborative Innovation Center of Yangtze River Delta Region Green Pharmaceuticals Zhejiang University of Technology Hangzhou PR China |
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