Fe- or co-catalyzed silylation-peroxidation of alkenes with hydrosilanes and T-hydro |
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| Authors: | Shenglin Lu Tian Tian Ran Xu Zhiping Li |
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| Institution: | Department of Chemistry, Renmin University of China, Beijing 100872, China |
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| Abstract: | The silylation-peroxidation of alkenes with hydrosilanes and T-hydro was developed by using iron or cobalt catalyst. The three-component protocol provided a practical method for synthesis of a variety of β-silyl peroxides. Excellent diastereoselectivity of the silylation-peroxidation of alkenes was achieved when internal alkenes were used. |
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| Keywords: | Silylation Peroxidation Difunctionalization Hydrosilane Alkene |
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