Epoxidation of vinyl cyanides by calcium hypochlorite under catalyst- and solvent-free conditions |
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| Authors: | F Mirhashemi MA Amrollahi |
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| Institution: | Department of Chemistry, Yazd University, Yazd, Iran |
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| Abstract: | In this paper, epoxidation of a wide range of alkenes by calcium hypochlorite (Ca(OCl)2) was investigated under catalyst- and solvent-free conditions. It was noticed that the highest yield was achieved with crushing, when the reaction was between vinyl cyanides and Ca(OCl)2. The structure of the synthesized epoxides was confirmed by IR, 1H and 13C NMR and elemental analysis. Short reaction times, the use of a simple experimental procedure, and reducing of energy consumption are other important advantages of our work that could be mentioned too. |
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| Keywords: | Epoxidation Calcium hypochlorite Catalyst-free Solvent-free Crushing |
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