Clip[5]arenes: A new family of molecular clips

Here we report the design and syntheses of two new triptycene-based rigid acyclic C-shaped hosts, clip5]arenes C5]OH and C5]ME, and the strong host–guest complexation between C5]OH and an electron-poor bipyridinium salt, paraquat G. The K_a value for the host–guest complex C5]OH???G was calculated to be (1.09?±?0.36)??×??10⁵?M^?1 in acetone by using a non-linear curve-fitting method based on the UV–vis absorption titration experiments. Furthermore, based on this new host–guest recognition motif, a novel pseudopolyrotaxane-like supramolecular structure was constructed with C5]OH threaded on polyviologen polymer VP-10.