Recent advances in transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes |
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| Authors: | Yi-Pan Li Zi-Qi Li Shou-Fei Zhu |
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| Institution: | 1. State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China;2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China |
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| Abstract: | The transition-metal-catalyzed reaction of diazo compounds with arenes or heteroarenes is an efficient and straightforward approach to functionalize aromatic compounds. This digest summarizes recent progresses on transition-metal-catalyzed asymmetric reactions of diazo compounds with electron-rich (hetero-) arenes, including C–H functionalization, cascade reaction, cyclopropanation, cycloaddition, Buchner reaction and intramolecular dearomatization. |
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| Keywords: | Asymmetric catalysis Diazo compounds Electron-rich (hetero-) arenes Transition-metal-catalysts Carbenes |
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