On the mechanism of cobalt(III) aminates pyrolysis |
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| Authors: | M A Ilyushin Yu S Tverjanovich A S Tverjanovich A O Aver’yanov A V Smirnov I V Shugalei |
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| Institution: | 1.St. Petersburg State Technological Institute (Technical University),St. Petersburg,Russia;2.St. Petersburg State University,St. Petersburg,Russia |
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| Abstract: | Pyrolysis of the complex (ato-N2)pentaammincobalt(III) perchlorate and the ligand 5-nitrotetrazole, and also of the initial complex aquapentaammincobalt(III) perchlorate was studied by the mass spectroscopy method. The leading oxidizer of ligands in the complexes is changed for the outer-sphere perchlorate ion at the pyrolysis temperature of ~250°C. |
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