Pd-catalyzed oxidative homo-coupling of acrylates and aromatic alkenes for the conjugated diene synthesis |
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| Authors: | Ting Zhu Zhen Li Fanhua Xiao Wei-Liang Duan |
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| Affiliation: | 1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;2. College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China |
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| Abstract: | We developed a bidentate monoanionic nitrogen ligand that was effective in the Pd-catalyzed oxidative homo-coupling reaction of acrylates and aromatic alkenes. In the presence of Pd(OAc)2/ligand several conjugated dienes were obtained in good yields with high stereoselectivities. |
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| Keywords: | Pd-catalysis Acrylates Aromatic alkenes Conjugated dienes |
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