Photocatalytic alkoxy radical-mediated transformations |
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Authors: | Jing-Jing Guo Anhua Hu Zhiwei Zuo |
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Institution: | School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China |
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Abstract: | Alkoxy radicals have been intensively studied as versatile synthetic intermediates with well-established reactivity and selectivity. Due to the difficulties associated with the generation of these transient and high-energy radicals, the utilization of the unique reactivity of alkoxy radicals in catalytic platforms has become a rather challenging task. Recent studies on the alkoxy radical-mediated transformations have benefited tremendously from advances in modern photoredox catalysis. In this digest, we aim to highlight reported transformations that utilize alkoxy radicals in a photocatalytic fashion, in particular, underline novel catalytic platforms which we anticipate will find broad application in the near future. |
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Keywords: | Photoredox catalysis Alkoxy radical Hydrogen atom transfer β-Scission Corresponding author |
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