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The investigation on the NH reactivity of pentacoordinate spirophosphoranes by H/D exchange and NMR experiments
Authors:Can Sun  Shuxia Cao  Pei Zhao  Wenwen Ma  Yanchun Guo  Yufen Zhao
Institution:1. The College of Chemistry and Molecular Engineering, The Key Laboratory of Chemical Biology and Organic Chemistry of Henan Province, Zhengzhou University, Zhengzhou 450052, PR China;2. Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, PR China
Abstract:Different pentacoordinate spirophosphoranes were investigated by H/D exchange and NMR tracking experiments. The H/D exchanged site of spirophosphoranes was confirmed to be the N/>H bond instead of the P<img style=
Keywords:H/D exchange experiment  NMR tracking experiment  Pentacoordinate spirophosphoranes
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