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Reaction-based fluorescent probe for detecting of sulfur dioxide derivatives and hydrazine via distinct emission signals
Authors:Yang Zhou  Fanwei Zeng  Yang Liu  Meng Li  Shuzhang Xiao  Jiaying Yan  Nuonuo Zhang  Kaibo Zheng
Affiliation:1. Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, College of Materials and Chemical Engineering, China Three Gorges University, Yichang 443002, PR China;2. College of Biological and Pharmaceutical Sciences, China Three Gorges University, Yichang 443002, PR China
Abstract:Recently, the construction of multiple analytes responsive fluorescent probes with distinct emission signals has attracted widely attention. Thus, we have designed and synthesized a new fluorescent probe, 2-(2-hydroxyphenyl)benzothiazole dye skeleton (HBT-1), for the detection of sulfur dioxide and hydrazine. Significant fluorescence enhancements in two distinct emission bands (λem?=?464?nm and 498?nm) were generated when HBT-1 reacted with sulfur dioxide derivatives or hydrazine, respectively. Furthermore, the probe HBT-1 response can be saturated surpurisingly at the low concentration (100?μM), shorter reaction time for sulfur dioxide derivatives, while a longer reaction time and greater concentration (400?μM) for hydrazine. In other words, the probe HBT-1 can detect sulfur dioxide derivatives without hydrazine interference at low analyte concentrations.
Keywords:Fluorescent probe  Sulfur dioxide derivatives  Hydrazine  Distinct emission signals
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