Stability of tetraoxides of chemical elements |
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Authors: | V. P. Shilov A. M. Fedoseev A. V. Gogolev |
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Affiliation: | 1.A.N. Frumkin Institute of Physical Chemistry and Electrochemistry,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | Published data on the synthesis of eight-valence iridium and some other elements, and also works casting doubt on the fact of preparing iron and some 5f-elements in the oxidation state +8 were analyzed. Supposed methods (nuclear-chemical and pulse radiolysis methods) for Pu(VIII) and Am(VIII) detection and the method of matrix isolation at a temperature of 4–6 K for stabilization of eight-valence in Fe, Pu, and Am were considered. |
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