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Useful methods for the synthesis of isopropylidenes and their chemoselective cleavage
Authors:Khiangte VanlaldinpuiaGhanashyam Bez
Affiliation:Department of Chemistry, North Eastern Hill University, Shillong 793022, India
Abstract:A catalytic amount of phosphotungstic acid (PTA) has been found to be a very effective catalyst for isopropylidenation of 1,2-diols and their deprotection at room temperature. The ease of handling, cost and activity of the catalyst, good to excellent yields and chemoselectivity for deprotection are some of the highlights of the reported method.
Keywords:Phosphotungstic acid   Isopropylidenation   Deisopropylidenation   Chemoselective
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