Hydrothermal Synthesis and Structure of [(PbCl2)μ-PyZ)1/2]n (Pyz = Pyrazine) |
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作者姓名: | LIAO Qiu-Xia ZHANG Jian QIN Ye-Yan YAO Yuan-Gen |
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作者单位: | State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,The Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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基金项目: | This work was supported by the National Natural Science Foundation of China (No. 20173063), the State Key Basic Research and Development Plan of China (001CB108906), and the NSF of Fujian Province (E0020001) |
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摘 要: | 1 INTRODUCTION Because of the flexibility of Pb(II) coordination sphere and the nonstereospecific nature of halide anions1], the chemistry of lead halide complexes has been developed in recent years. Especially PbX2- based coordination polymers with nitrogen-contain- ing Lewis bases have attracted renewed interest2~11]. The choice of ligand and the reaction condition are of great importance in determining the final topo- logy of the supramolecular materials. But the avail- able struc…
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