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The Raman spectra of serine and 3,3-dideutero-serine in aqueous solution
Affiliation:1. Department of Chemistry, University of Coimbra, 3004-535 Coimbra, Portugal;2. Department of Biochemistry, Case Western Reserve University, 10900 Euclid Ave., Cleveland, OH 44106-4935, USA
Abstract:The Raman spectra of serine [α-amino-β-hydroxypropionic acid; HOsingle bondCH2single bondCH(NH3)+single bondCOO] and 3,3-dideutero-serine [HOsingle bondCD2single bondCH(NH3)+single bondCOO] in aqueous solution were studied in the range 4000–300 cm−1. The data obtained for the deuterated compound are novel and provide compelling evidence that previously reported assignments for the undeuterated amino acid should be revised.
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