Synthesis and characterization of new poly(azomethine ester)s having phenylthiourea units |
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Authors: | Benjamin Joy Vasanthi Lingam Ravikumar |
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Institution: | Department of Chemistry, C.B.M. College, Coimbatore 641042, Tamilnadu, India |
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Abstract: | New polyesters having azomethine and phenylthiourea groups in the polymer backbone were synthesized by interfacial polycondensation method. The dihydroxy monomer N-(4-hydroxy-3-methoxybenzal) N′-(4′-hydroxyphenyl)thiourea was condensed with six diacid chlorides: terephthaloyl, isophthaloyl, azeloyl, suberoyl, pimeloyl and adipolyl chlorides. The resulting polyesters were characterized by viscosity, IR, NMR and TGA analysis. The wholly aromatic poly(azomethine ester) derived from terephthaloyl chloride when blended with polyaniline/NH4OH, polyaniline/HCl and pure polyaniline shows conductance in the range 3.2 × 10−3-0.91 × 10−1 S cm−1. |
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Keywords: | Poly(azomethine ester)s Phenylthiourea Polyaniline blends Electrical conductivity |
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