Ionic transport studies on (PEO)6:NaPO3 polymer electrolyte plasticized with PEG400

Conduction characteristics of the poly(ethylene oxide) based new polymer electrolyte (PEO)₆:NaPO₃, plasticized with poly(ethylene glycol) are investigated. Free standing flexible electrolyte films of composition (PEO)₆:NaPO₃ + x wt.% PEG₄₀₀ (30 ? x ? 70) are prepared by solution casting method. A combination of X-ray diffraction (XRD), optical microscopy and differential scanning calorimetry (DSC) studies have indicated enhancement in the amorphous phase of polymer due to the addition of plasticizer. Further, a reduction in the glass transition temperature observed from the DSC result has inferred increase in the flexibility of the polymer chains. The cationic transport number (t_Na⁺) of 0.42 determined through combined ac-dc technique has confirmed ionic nature of conducting species. Ionic conductivity studies are carried out as a function of composition and temperature using complex impedance spectroscopy. The electrolyte with maximum PEG₄₀₀ content has exhibited an enhancement in the conductivity of about two orders of magnitude compared to the host polymer electrolyte. The complex impedance data is analyzed in conductivity, permittivity and electric modulus formalism in order to throw light on transport mechanism. A solid state electrochemical cell based on the above polymer electrolyte with a configuration Na|SPE|(I₂ + acetylene black + PEO) has exhibited an open circuit voltage of 2.94 V. The discharge characteristics are found to be satisfactory as a laboratory cell.