Morphological effect on spectral property of poly(9,9-dihexylfluorene-alt-2,5-dihexyloxybenzene) films |
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| Authors: | Meng Wang |
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| Affiliation: | Key Laboratory of Molecular Engineering of Polymers of Ministry of Education, Department of Macromolecular Science, Laboratory of Advanced Materials, Fudan University, Shanghai 200433, People’s Republic of China |
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| Abstract: | In this study the optical property and film morphology of a conjugated polymer, poly(9,9-dihexylfluorene-alt-2,5-dihexyloxybenzene) (PF6OC6), are investigated. It is found that the intensity of the 0-1 emission relative to the 0-0 emission in the PL spectra and the full width at the half-maximum (fwhm) of PL spectra of the PF6OC6 films decrease firstly and then increase with increasing the annealing temperature. The polymer films also exhibit different morphological features after annealing at different temperatures. The optical and morphological results suggest that the vibronic structure of PF6OC6 is closely related to the film morphology, and its formation is enhanced in the amorphous (or less ordered) films and inhibited in the ordered films. |
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| Keywords: | Conjugated polymer Films Morphology Annealing Photophysics |
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