| 新型三齿含膦配体的Ni(Ⅱ)配合物的合成和晶体结构 |
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| 引用本文： | 程林,欧阳超琴,杨玲.新型三齿含膦配体的Ni(Ⅱ)配合物的合成和晶体结构[J].无机化学学报,2005,21(1):70-72. |
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| 作者姓名： | 程林 欧阳超琴 杨玲 |
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| 作者单位： | 1. 安徽师范大学化学与材料科学学院,芜湖,241000
2. 昆明理工大学生物与化学工程学院,昆明,650224 |
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| 摘 要： | A new tridentate Ni(Ⅱ) complex {Ni(H2O)3Ph2(o-Ph-N-C7H7N)]PO}Cl2 was synthesized by the reaction of a new ligand Ph2(o-Ph-N-C7H7N)]PO with NiCl2 in CH3CH2OH. The complex was characterized by X-ray single crystal diffraction. The crystal structure of the complex belongs to monoclinic space group P22/n, a=1.259 28(9) nm, b=1.201 24(8) nm, c=2.039 03(14) nm, V=3.016 8(4) nm-3, Z=4, and R2=0.047 1, wR2=0.120 5. And a molecular CH2Cl2 is filled in the crystal structure. CCDC: 241832.
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| 关 键 词： | 三齿配体 镍配合物 晶体结构 合成 |
| 文章编号： | 1001-4861(2005)01-0070-03 |
| 收稿时间： | 4/6/2004 12:00:00 AM |
| 修稿时间： | 2004年4月6日 |
Synthesis and Crystal Structure of a New Tridentate Ni(Ⅱ) Complex {Ni(H2O)3[Ph2(o-Ph-N-C7H7N)]PO}Cl2 |
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| CHENG Lin,OUYANG Chao-Qin and YANG Ling.Synthesis and Crystal Structure of a New Tridentate Ni(Ⅱ) Complex {Ni(H2O)3[Ph2(o-Ph-N-C7H7N)]PO}Cl2[J].Chinese Journal of Inorganic Chemistry,2005,21(1):70-72. |
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| Authors: | CHENG Lin OUYANG Chao-Qin and YANG Ling |
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| Institution: | School of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000,Institute College of Biological and Chemical Engineering in Kunmming University of Science and Technology, Kunming 650224 and Institute College of Biological and Chemical Engineering in Kunmming University of Science and Technology, Kunming 650224 |
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| Abstract: | |
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| Keywords: | tridentate ligand Ni complex crystal structure synthesis |
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