Comparative Study of Five Outcrop Chalks Flooded at Reservoir Conditions: Chemo-mechanical Behaviour and Profiles of Compositional Alteration

This study presents experimental results from a flooding test series performed at reservoir conditions for five high-porosity Cretaceous onshore chalks from Denmark, Belgium and the USA, analogous to North Sea reservoir chalk. The chalks are studied in regard to their chemo-mechanical behaviour when performing tri-axial compaction tests while injecting brines (0.219 mol/L \(\hbox {MgCl}_{2}\) or 0.657 mol/L NaCl) at reservoir conditions for 2–3 months (T = 130 \(^\circ \hbox {C}\); 1 PV/d). Each chalk type was examined in terms of its mineralogical and chemical composition before and after the mechanical flooding tests, using an extensive set of analysis methods, to evaluate the chalk- and brine-dependent chemical alterations. All \(\hbox {MgCl}_{2}\)-flooded cores showed precipitation of Mg-bearing minerals (mainly magnesite). The distribution of newly formed Mg-bearing minerals appears to be chalk-dependent with varying peaks of enrichment. The chalk samples from Aalborg originally contained abundant opal-CT, which was dissolved with both NaCl and \(\hbox {MgCl}_{2}\) and partly re-precipitated as Si-Mg-bearing minerals. The Aalborg core injected with \(\hbox {MgCl}_{2}\) indicated strongly increased specific surface area (from 4.9 \(\hbox {m}^{2}\hbox {/g}\) to within 7–9 \(\hbox {m}^{2}\hbox {/g}\)). Mineral precipitation effects were negligible in chalk samples flooded with NaCl compared to \(\hbox {MgCl}_{2}\). Silicates were the main mineralogical impurity in the studied chalk samples (0.3–6 wt%). The cores with higher \(\hbox {SiO}_{2}\) content showed less deformation when injecting NaCl brine, but more compaction when injecting \(\hbox {MgCl}_{2}\)-brine. The observations were successfully interpreted by mathematical geochemical modelling which suggests that the re-precipitation of Si-bearing minerals leads to enhanced calcite dissolution and mass loss (as seen experimentally) explaining the high compaction seen in \(\hbox {MgCl}_{2}\)-flooded Aalborg chalk. Our work demonstrates that the original mineralogy, together with the newly formed minerals, can control the chemo-mechanical interactions during flooding and should be taken into account when predicting reservoir behaviour from laboratory studies. This study improves the understanding of complex flow reaction mechanisms also relevant for field-scale dynamics seen during brine injection.