Assembly of nitrogen-containing heterocycles initiated by the aza-Michael reaction |
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Authors: | A. Yu. Rulev |
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Affiliation: | 1.A. E. Favorsky Irkutsk Institute of Chemistry,Siberian Branch of the Russian Academy of Sciences,Irkutsk,Russian Federation |
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Abstract: | The aza-Michael reaction is considered as the most popular method for the carbon–nitrogen bond formation and the shortest way to β-aminocarbonyl compounds, including β-amino acids and their derivatives. In many cases, conjugate addition of nitrogen-centered nucleophiles to the activated multiple bond triggers a series of cascade transformations being completed by the formation of heterocycles and analogs of natural compounds. The review summarizes the most important advances in the aza-Michael reaction-initiated synthesis of nitrogen-containing heterocycles from unsaturated ketones and enoates. |
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