首页 | 本学科首页   官方微博 | 高级检索  
     检索      

3-硝基-1,3,4-三唑-5-酮金属(Li,Na, Pb,Cu)盐的制备反应热动力学
引用本文:李娜,赵凤起,高红旭,胡荣祖,肖立柏,姚二岗,黄新萍,常佩.3-硝基-1,3,4-三唑-5-酮金属(Li,Na, Pb,Cu)盐的制备反应热动力学[J].物理化学学报,2013,29(10):2101-2106.
作者姓名:李娜  赵凤起  高红旭  胡荣祖  肖立柏  姚二岗  黄新萍  常佩
作者单位:Laboratory of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
基金项目:国家自然科学基金(21173163)和燃烧与爆炸技术重点实验室基金(9140C350307110C3506)资助项目
摘    要:在常压、298.15 K条件下, 用RD496-2000微量热仪开展了3-硝基-1,3,4-三唑-5-酮(NTO)金属(Li, Na,Pb, Cu)盐制备反应的热动力学研究, 得到了反应过程中的热力学参数(活化焓、活化熵和活化自由能), 速率常数和动力学参数(活化能、指前因子和反应级数), 还得到了在25-40℃范围内NTO金属(Li, Na, Pb, Cu)盐制备反应过程的反应焓. 结果表明, NTO金属(Li, Na, Pb, Cu)盐的制备反应较容易发生. 基于Hess定律, 得到了ΔfHm0 (Li(NTO)·2H2O, aq, 298.15 K)和ΔfHm0 (Na(NTO)·H2O, aq, 298.15 K)的值.

关 键 词:NTO金属盐  制备反应  微量热仪  热动力学  
收稿时间:2013-06-03
修稿时间:2013-07-15

Thermokinetics of the Formation Reactions of Metal (Li,Na, Pb,Cu) Salts of 3-Nitro-1,2,4-triazol-5-one
LI Na,ZHAO Feng-Qi,GAO Hong-Xu,HU Rong-Zu,XIAO Li-Bai,YAO Er-Gang,HUANG Xin-Ping,CHANG Pei.Thermokinetics of the Formation Reactions of Metal (Li,Na, Pb,Cu) Salts of 3-Nitro-1,2,4-triazol-5-one[J].Acta Physico-Chimica Sinica,2013,29(10):2101-2106.
Authors:LI Na  ZHAO Feng-Qi  GAO Hong-Xu  HU Rong-Zu  XIAO Li-Bai  YAO Er-Gang  HUANG Xin-Ping  CHANG Pei
Institution:Laboratory of Science and Technology on Combustion and Explosion, Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China
Abstract:The thermokinetics of the formation reactions of metal (Li, Na, Pb, Cu) salts of 3-nitro-1,2,4-triazol- 5-one (NTO) was studied using a microcalorimeter. On the basis of experimental and calculated results, three thermodynamic parameters (activation energy, pre-exponential constant, and reaction order), rate constant, three thermokinetic parameters (activation enthalpy, activation entropy, and activation free energy) and the enthalpies of the reactions to prepare the metal salts of NTO in the temperature range of 25-40℃ were obtained. The title reactions occur easily in the studied temperature range. Based on Hess' law, the values of ΔfHm0 (Li(NTO)·2H2O, aq, 298.15 K) and ΔfHm0 (Na(NTO)·2H2O, aq, 298.15 K) are obtained.
Keywords:Metal salts of 3-nitro-1  2  4-triazol-5-one  Formation reaction  Microcalorimeter  Thermokinetics
点击此处可从《物理化学学报》浏览原始摘要信息
点击此处可从《物理化学学报》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号