Reactivity of coordinated O2? towards. One-electron oxidants |
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| Authors: | V M Berdnikov L L Makarshin and L S Ryvkina |
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| Institution: | (1) Institute of Chemical Kinetics and Combustion, Novosibirsk, USSR |
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| Abstract: | Ion-radical complexes Ti(IV) (O
2
–
) are unreactive towards most oxidants except Ce(IV) and Cr2O
7
2–
. The one-electron redox potential for the O2 coord./O
2 coord.
–
couple lies between 1 and 1.6 V.
           -   O
2
–
Ti(IV)          ,    Ce(IV) Cr2 O
7
2–
.   - O2 ./O
2
–
.   1 1,6  .
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| Keywords: | |
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