|
|||||
|
|
Enynones in organic synthesis. I. Spiroannulation by tandem oxy-cope rearrangement-electrocyclic ring closure |
|
| Authors: | Peter A Jacobi Lisa M Armacost Joseph I Kravitz Michael J Martinelli Harold G Selnick |
| Institution: | Hall-Atwater Laboratories, Wesleyan University Middletown, Connecticut 06457 U.S.A. |
| Abstract: | Bis-acetylenic alcohols of proper design undergo a facile oxy-Cope rearrangement to afford mixtures of E- and Z-enynones. These latter compounds afford methylenecyclopentenones upon enolization and electrocyclic ring closure. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |