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Metallomicelles of palladium(II) complexes as efficient catalysts for the Suzuki–Miyaura reaction in neat water |
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| Authors: | Yan Liu Xiaowei Ma Jianwei Xie Ping Liu Bin Dai Ren He |
| Institution: | 1. School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, , Shihezi, 832003 China;2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, , Dalian, 116012 China |
| Abstract: | Metallomicelles of palladium(II) complex 4 are found to be an efficient catalyst for Suzuki–Miyaura reactions of aryl bromides substituted with a long alkyl chain and arylboronic acids at 80 °C in neat water. The reactions proceed smoothly to generate the corresponding biaryl compounds in moderate to excellent yields. Various biphenyl derivatives were successfully obtained by complex 4 catalysis of the Suzuki–Miyaura reactions in the absence of any surfactants in neat water. Copyright © 2013 John Wiley & Sons, Ltd. |
| Keywords: | metallomicelles palladium(II) complexes Suzuki– Miyaura reaction water liquid crystalline compounds |