Synthesis and characterization of Pd(II) complexes of 2‐ and 3‐thiophenecarbaldehyde immobilized on silica obtained from sepiolite |
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| Authors: | Jorge Corral Manuel Mora César Jiménez‐Sanchidrián José Rafael Ruiz |
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| Affiliation: | Departamento de Química Orgánica, Universidad de Córdoba, Campus de Rabanales, Edificio Marie Curie, , 14014 Córdoba, Spain |
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| Abstract: | Silica obtained by acid treatment of sepiolite was used as a support for catalysts consisting of palladium complexes of 2‐ and 3‐thiophenecarbaldehyde. The support and the catalysts were characterized by X‐ray diffraction, and solid‐state 29Si and 13C nuclear magnetic resonance spectroscopies. The supported palladium catalysts were used in the Suzuki reaction of bromobenzene with phenylboronic acid. Copyright © 2013 John Wiley & Sons, Ltd. |
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| Keywords: | Pd(II) complexes silica sepiolite Suzuki reaction |
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