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One‐Pot Zinc‐Promoted Asymmetric Alkynylation/Brook‐Type Rearrangement/Ene–Allene Cyclization: Highly Selective Formation of Three New Bonds and Two Stereocenters in Acyclic Systems
Authors:Polina Smirnov  Dr Jomon Mathew  Dr Anne Nijs  Einat Katan  Dr Miriam Karni  Prof Dr Carsten Bolm  Prof Dr Yitzhak Apeloig  Prof Dr Ilan Marek
Institution:1. Schulich Faculty of Chemistry and the Lise Meitner–Minerva Center for Computational Quantum Chemistry, Technion‐Israel Institute of Technology, Technion City, Haifa 32000 (Israel);2. Institute für Organische Chemie der RWTH Aachen University, Landoltweg 1, 52056 Aachen (Germany)
Abstract:
Keywords:acyl silanes  alkynylation  asymmetric synthesis  Brook rearrangement  zinc
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