Selective hydroformylation of various olefins using diphosphinite ligands |
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| Authors: | Shoeb R. Khan Bhalchandra M. Bhanage |
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| Affiliation: | Department of Chemistry, Institute of Chemical Technology, , Mumbai, India |
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| Abstract: | Novel diphosphinite ligands are synthesized by the reaction of various derivatives of 1,3‐diols with chlorodiphenylphosphine. The synthesized ligands exhibited considerable impact on hydroformylation of various olefins with excellent regioselectivity toward branched aldehyde. The effect of solvent, temperature, pressure and catalyst loading on the hydroformylation reaction is also described. The synthesized diphosphinite ligands with rhodium precursor works under milder reaction conditions as compared to traditional phosphine and phosphite‐based ligands. Copyright © 2013 John Wiley & Sons, Ltd. |
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| Keywords: | hydroformylation olefins bis(phosphinite) ligand regioselective homogeneous catalysis |
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