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Highly stereoselective addition reactions of metallated trans-1,3-dithiane-1,3-dioxide to aldehydes |
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| Authors: | Varinder K Aggarwal Richard J Franklin and Martin J Rice |
| Institution: | a School of Chemistry, University of Bath, Bath, BA2 7AY, UK b ICI Agrochemicals, Jealott's Hill Research Station, Bracknell, RG12 6EY, UK |
| Abstract: | The sodium anion of trans-1,3-dithiane-1,3-dioxide reacts with unhindered aromatic and heteroaromatic aldehydes to give adducts with 95:5 to 97:3 diastereoselectivity. |
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