Long-range coulomb interaction of electrons of 4f orbitals in impurity centers Yb3+: KZnF3, CsCaF3, and Sm3+: CaF2 |
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Authors: | O. A. Anikeenok |
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Affiliation: | 1. Kazan (Volga Region) Federal University, ul. Kremlevskaya 18, Kazan, 420008, Tatarstan, Russia
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Abstract: | Expressions for calculating the matrix elements of the Coulomb interaction of f electrons of the isolated ion with an infinite crystal lattice have been obtained. The contribution of this interaction to the parameters of the crystal field in impurity centers Yb3+: KZnF3, CsCaF3, and Sm3+: CaF2 has been calculated. |
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