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Site-selective multi-emitter gold-silver metallopolymers: A novel class of self-assembled materials |
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| Authors: | Inés Soldevilla Montserrat Santamaría-Paganini M. Elena Olmos Miguel Monge José M. López-de-Luzuriaga María Rodríguez-Castillo |
| Affiliation: | Departamento de Química, Centro de Investigación en Síntesis Química (CISQ), Complejo Científico Tecnológico, Universidad de la Rioja, Madre de Dios 53, Logroño, La Rioja, 26006 Spain |
| Abstract: | New luminescent heterometallopolymers [(Au-C6F5)m(AgOSO2CF3)n (PVP)] with different Au:Ag molar ratios were synthesized. The luminescent emissions of these polymers are strongly dependent on the temperature, excitation wavelengths, and the Au(I):Ag(I) molar ratio. The incorporation of a precise amount of Ag(I) atoms in the backbone of [(Au-C6F5)m(PVP)] metallopolymer allows a controlled tuning of the emission energy in the green-blue range. |
| Keywords: | computational studies gold(I) metallopolymers silver(I) site-selective emitters |