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Kinetics of radiolytic oxidation of ferrous ions in some aqueous aerated systems
Authors:B L Gupta
Institution:

Radiological Physics Division, Bhabha Atomic Research Centre, Trombay, Bombay 400085, India

Abstract:The oxidation of ferrous ions by organic peroxy radicals at different doses is non-linear, however, the plots of inverse of ferric ion concentration against inverse of dose are linear. This behavior is explained by a set of three general reactions. Some of the organic free radicals produced in these systems either react with O2 forming peroxy radicals or they get oxidized by ferric ions. Other organic free radicals do not involve in the above competition and react with O2 only.
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