Experimental and theoretical evidence of the first Au(i)...Bi(iii) interaction |
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| Authors: | Fernández Eduardo J Laguna Antonio López-de-Luzuriaga José M Monge Miguel Nema Mihai Olmos M Elena Pérez Javier Silvestru Cristian |
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| Affiliation: | Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, UA-CSIC. Complejo Científico-Tecnológico, 26004, Logro?o, Spain. eduardo.fernandez@dq.unirioja.es |
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| Abstract: | Complex [Au(C6F5)2][Bi(C6H4CH2NMe(2)-2)2] displays the first example of an interaction between Au(I) and Bi(III), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%). |
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