Intramolecular palladium-catalyzed direct arylation of alkenyl triflates |
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| Authors: | Cruz Ana C F Miller Neil D Willis Michael C |
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| Institution: | Department of Chemistry, University of Bath, Bath, BA2 7AY, UK. |
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| Abstract: | A catalyst generated from Pd(OAc)2 and dppp is effective for the direct intramolecular arylation of alkenyl triflates. Conjugated alkene-arene-containing carbocycles are produced in good yield. The process tolerates a variety of aryl substituents as well a simple heteroaryl groups. Electron-deficient aryl rings deliver faster reactions. |
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