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Intramolecular palladium-catalyzed direct arylation of alkenyl triflates
Authors:Cruz Ana C F  Miller Neil D  Willis Michael C
Institution:Department of Chemistry, University of Bath, Bath, BA2 7AY, UK.
Abstract:A catalyst generated from Pd(OAc)2 and dppp is effective for the direct intramolecular arylation of alkenyl triflates. Conjugated alkene-arene-containing carbocycles are produced in good yield. The process tolerates a variety of aryl substituents as well a simple heteroaryl groups. Electron-deficient aryl rings deliver faster reactions.
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