Influence of chemical bonding on X-ray spectra of different aluminium compounds |
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Affiliation: | 1. School of Materials and Chemical Engineering, Xi''an Technological University, Xi''an, Shaanxi 710021, China;2. State Key Laboratory for Mechanical Behavior of Materials, Xi''an Jiaotong University, Xi''an, Shaanxi 710049, China |
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Abstract: | Five minerals containing aluminium in different crystal configurations are studied. The different kinds of chemical bonding between aluminium and oxygen originate molecular orbitals with energy levels and transition probabilities varying from one compound to another. This effect appears as shifts and changes in relative intensities of Kα emission lines and as modifications of the Kβ characteristic spectrum. In the present work, the aluminium K characteristic spectra obtained by means of an electron microprobe with a wavelength dispersive system are compared for topaz, albite, spodumene, biotite and corundum. |
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