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Evaluation of a compact spectrograph for in-situ and stand-off Laser-Induced Breakdown Spectroscopy analyses of geological samples on Mars missions
Institution:1. Embrapa Instrumentation, Rua XV de Novembro, 1452, CEP 13560-970 São Carlos, SP, Brazil;2. Institute of Inorganic Methodologies and Plasmas, CNR, Bari, 70126 Bari, Italy;3. Physics Institute of São Carlos, University of São Paulo, IFSC-USP, Av. Trabalhador são-carlense, 400 Pq. Arnold Schimid, 13566-590 São Carlos, SP, Brazil;1. GeoRessources lab, Université de Lorraine, Nancy, France;2. Los Alamos National Laboratory, Los Alamos, NM, USA;3. University of NM, Albuquerque, USA;4. IRAP, Toulouse, France;5. Museum National d''Histoire Naturelle, Paris, France;6. Planetary Science Institute, Tucson, AZ, USA;7. Delaware State University, USA;1. Fuel Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085, India;2. Department of Physics, University of Allahabad, Allahabad 211002, India;3. Lawrence Berkeley National Laboratory, University of California, Berkeley, CA 94720, USA;1. State Key Laboratory of Electrical Insulation and Power Equipment, Xi''an Jiaotong University, Xi''an 710049, China;2. Key Laboratory for Physical Electronics and Devices of the Ministry of Education, Xi''an Jiaotong University, Xi''an 710049, China;1. Optical Science Center for Applied Research, Delaware State University, Dover, DE 19901, USA;2. Los Alamos National Laboratory, Los Alamos, NM, USA;3. Institut de Recherche en Astophysique et Planetologie (IRAP), Universite Paul Sabatier, Toulouse, France;4. Planetary Science Institute, Flagstaff, AZ, USA;5. Dept. of Astronomy, Mount Holyoke College, South Hadley, MA, USA;6. Institut des Sciences de la Terre, Universite’ Grenoble l-CNRS, Grenoble, France;7. CNRS, Georessources, Vandoeuvre les Nancy, France
Abstract:Laser-induced Breakdown Spectroscopy (LIBS) is actively under development for future use on surface probes to Mars. The analytical method can be deployed for in-situ and/or stand-off analysis with the latter embodiment providing the greatest advantages compared to previous and current elemental analysis methods used for planetary surface analysis. For this application, LIBS must be thoroughly investigated in terms of analytical capabilities and flight-rated instruments must be developed. Because of the low pressure of the predominantly CO2 atmosphere on Mars, studies are needed to understand analytical requirements and to determine performance under these conditions. Stand-off analysis demands the most stringent requirements on instrumentation. Therefore, it must be determined if the high performance components that are normally used in a typical LIBS laboratory setup, which are generally not optimized for small size and weight, are essential to obtain the maximum scientific return from a mission. A key component of a LIBS apparatus is the detection system consisting of a spectrograph and a detector. Here we present an evaluation of one design of a compact spectrograph (Ocean Optics HR2000) for in-situ and stand-off LIBS analyses of geological samples under Mars atmospheric conditions.
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