State-of-the-art and recent progress in resorcinarene-based cavitand |
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| Institution: | 1. Key Laboratory of Light Conversion Materials and Technology of Shandong Academy of Sciences, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China;2. College of Chemistry and Materials Science, Northwest University, Xi''an 710069, China;3. College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China;4. Institute of Materia Medica, Chinese Academy of Medical Sciences, Beijing 100050, China;5. Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200438, China;6. Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230026, China;7. School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China;8. Key Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China;9. College of Chemistry, Sichuan University, Chengdu 610065, China;10. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China;1. Department of Chemistry and the MOE Key Laboratory of Spectrochemical Analysis & Instrumentation, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;2. Department of Chemistry, Taiyuan Normal University, Jinzhong 030619, China;3. Department of Electronic Science, Xiamen University, Xiamen 361005, China;1. Key Laboratory of Pollution Process and Environmental Criteria, Ministry of Education, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China;2. Tianjin Key Laboratory of Environmental Technology for Complex Trans-Media Pollution, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China;3. Tianjin Advanced Water Treatment Technology International Joint Research Center, College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China |
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| Abstract: | Compartmentalization in the biological world brings excellent efficiency and specificity to the formation of complex compounds, inspiring supramolecular chemists to continuously search for defined spaces that can mimic such natural binding sites. Bowl-shaped cavitands built up from resorcinarenes (RA) present rigid and preorganized concave surfaces, which are capable of mimicking the molecular recognition properties of enzymes. The versatile scaffold of RA endows the cavitand with terrific variety and excellent binding behavior. This review provides a comprehensive overview over the structural modification to date in the high attention field of RA-based cavitands development. Different strategies for synthesizing diverse cavitands, such as small cavity cavitands, wider cavity cavitands, deep cavity cavitands, biscavitands, and asymmetric cavitands, are discussed in details. Furthermore, insights into their applications including catalysis, separations and sensing are provided. |
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