| 噻唑硫磷的结构研究 |
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| 引用本文： | 朱静,郑虎,翁玲玲,李章万.噻唑硫磷的结构研究[J].化学研究与应用,2005,17(3):355-356. |
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| 作者姓名： | 朱静 郑虎 翁玲玲 李章万 |
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| 作者单位： | 四川大学华西药学院,四川,成都,610041;四川大学华西药学院,四川,成都,610041;四川大学华西药学院,四川,成都,610041;四川大学华西药学院,四川,成都,610041 |
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| 摘 要： | 噻唑硫磷(fosthiazate)是一种新型、高效的有机磷农药。它是由2-氧化噻唑烷与S-仲丁基-O-乙基硫代磷酰氯通过取代反应制得，其化学名为O-乙基-S-仲丁基-2-氧代-1，3-噻唑烷-3-基硫代膦酸酯，结构式如下：
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| 关 键 词： | 噻唑硫磷 结构 解析 核磁共振 二维核磁技术 |
| 文章编号： | 1004-1656(2005)03-0355-02 |
| 修稿时间： | 2004年2月19日 |
Structure study of fosthiazate |
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| ZHU Jing,ZHENG Hu,WENG Ling-Ling,LI Zhang-wan.Structure study of fosthiazate[J].Chemical Research and Application,2005,17(3):355-356. |
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| Authors: | ZHU Jing ZHENG Hu WENG Ling-Ling LI Zhang-wan |
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| Abstract: | In this paper,we studied the structure of fosthiazate by kinds of spectral techniques.The absorption in the UV spectrum coincides with the structure of fosthiazate.The main characteristic adsorption bands in the IR spectrum and fragment ions in the mass spectrum could be assigned rationally according to the structure of fosthiazate.In addition,several kinds of two-dimensional NMR techniques(~1H-~1H COSY,HMBC and HMQC)which could provide valuable information were used for the assignment of ~1H NMR and ()~(13)C NMR signals.Combining all above techniques with the element analysis,we verified the structure of fosthiazate. |
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| Keywords: | fosthiazate structure analyse NMR 2D-NMR |
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