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Molecular beam deflection experiments on mixed clusters |
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| Authors: | I Compagnon R Antoine D Rayane Ph Dugourd M Broyer |
| Institution: | (1) Laboratoire de Spectrométrie Ionique et Moléculaire, Université Lyon I et CNRS, 43 boulevard du 11 novembre 1918, 69622 Villeurbanne Cedex, France, FR |
| Abstract: | Gas phase Ti-C60 clusters are studied by molecular beam electric deflection. The permanent dipole moment of the TiC60 molecule is determined. It is equal to 8.1±1.5 D. This dipole is due to a transfer of electron from the transition metal atom to the C60 cage. No dipole is observed for Ti(C60)2 molecules. This is in agreement with the symmetrical dumbbell-like structure that has been previously proposed. Received 22 November 2000 |
| Keywords: | PACS 33 15 Kr Electric and magnetic moments (and derivatives) polarizability and magnetic susceptibility – 36 40 Cg Electronic and magnetic properties of clusters – 61 48 +c Fullerenes and fullerene-related materials |
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