Photoelectron spectra of chromium tetranitrosyl |
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| Authors: | E.W. Plummer G. Loubriel D. Rajoria M.R. Albert L.G. Sneddon W.R. Salaneck |
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| Affiliation: | Department of Physics and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, Pa. 19104 U.S.A.;Department of Chemistry and Laboratory for Research on the Structure of Matter, University of Pennsylvania, Philadelphia, Pa. 19104 U.S.A.;Xerox Webster Research Center, Webster, N.Y. 14580 U.S.A. |
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| Abstract: | The ultraviolet and X-ray-excited photoelectron spectra of Cr(NO)4 are reported. The electron binding energies, shake-up spectra, relative peak intensities and the Auger peak kinetic energies have been measured, and are compared to the spectra from gas-phase NO, from NO adsorbed on a transition metal surface, and to SCF-MS calculations. The theoretical calculations are utilized to obtain ionization energies and charge distributions, and consequently to discuss the bonding in nitrosyl complexes. |
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