Tuning of spin crossover equilibrium in catecholatoiron(III) complexes by supporting ligands |
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Authors: | Hitomi Yutaka Higuchi Masakazu Minami Hisataka Tanaka Tsunehiro Funabiki Takuzo |
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Affiliation: | Department of Molecular Engineering, Kyoto University, Kyoto Daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. hitomi@moleng.kyoto-u.ac.jp |
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Abstract: | Introduction of electron-withdrawing groups on co-ligands effectively raises the spin crossover temperature of catecholatoiron(III) complexes and induces a significant amount of the low spin species in solution even at around room temperature. |
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