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Tuning of spin crossover equilibrium in catecholatoiron(III) complexes by supporting ligands
Authors:Hitomi Yutaka  Higuchi Masakazu  Minami Hisataka  Tanaka Tsunehiro  Funabiki Takuzo
Affiliation:Department of Molecular Engineering, Kyoto University, Kyoto Daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. hitomi@moleng.kyoto-u.ac.jp
Abstract:Introduction of electron-withdrawing groups on co-ligands effectively raises the spin crossover temperature of catecholatoiron(III) complexes and induces a significant amount of the low spin species in solution even at around room temperature.
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