Reactivity of coordinated O2? ion-radicals in the oxidation of organic compounds |
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| Authors: | V M Berdnikov L L Makarshin and L S Ryvkina |
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| Institution: | (1) Institute of Kinetics and Combustion, Novosibirsk, USSR |
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| Abstract: | By the flow ESR method, the rates of the reaction of the radical complex Ti(IV)(O
2
–
) with some aromatic compounds in aqueous solution have been measured. An elementary step of these reactions seems to be one-electron oxidation with the formation of a substrate cation-radical.
                     -     Ti(IV)(O
2
–
)   .  -  -.
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| Keywords: | |
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