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Sulfur ylide-initiated thio-claisen rearrangements. The synthesis of highly substituted indolines |
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| Authors: | Novikov Alexei V Kennedy Abigail R Rainier Jon D |
| Affiliation: | Department of Chemistry, The University of Arizona, Tucson, Arizona 85721, USA. |
| Abstract: | The coupling of rhodium carbenoids from vinyl diazoacetates with 2-thio-3-alkyl indoles was found to generate C(3) quaternary substituted indolines via a thionium ylide-initiated [3,3]-sigmatropic rearrangement. |
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