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Synthesis and Fluorescence of alt-Copoly[1, 4-divinylenebenzene/1, 4-bis(dimethylsilylene)benzene]
引用本文:XiaoBangDUAN GuoPingCAI WilliamP.WEBER PingLU. Synthesis and Fluorescence of alt-Copoly[1, 4-divinylenebenzene/1, 4-bis(dimethylsilylene)benzene][J]. 中国化学快报, 2005, 16(3): 405-408
作者姓名:XiaoBangDUAN GuoPingCAI WilliamP.WEBER PingLU
作者单位:[1]DepartmentofChemistry,ZhejiangUniversity,Hangzhou310027 [2]K.B.andD.P.LokerHydrocarbonResearchInstitute,DepartmentofChemistryUniversityofSouthernCalifornia,LosAngeles,CA90089-1661,USA
摘    要:Silicon inserted n conjugated copolymer was synthesized by Heck reaction with moderate molecular weight. This silicon containing copolymer is thermally stable to 400℃, while emission of this polymer is blue-shifted compared with polyphenylenevinylene greenish emission. It shows potential application as organic emitter in OLED.

关 键 词:合成 荧光性质 共聚体 1  4-二次亚乙烯基苯 1  4-二(二甲基亚甲硅基)苯 Heck反应

Synthesis and Fluorescence of alt-Copoly[1,4-divinylenebenzene/1,4-bis(dimethylsilylene)benzene]
Xiao Bang DUAN,Guo Ping CAI,William P. WEBER,Ping LU. Synthesis and Fluorescence of alt-Copoly[1,4-divinylenebenzene/1,4-bis(dimethylsilylene)benzene][J]. Chinese Chemical Letters, 2005, 16(3): 405-408
Authors:Xiao Bang DUAN  Guo Ping CAI  William P. WEBER  Ping LU
Affiliation:Xiao Bang DUAN1,Guo Ping CAI1,William P. WEBER2,Ping LU1* 1Department of Chemistry,Zhejiang University,Hangzhou 310027 2K. B. and D. P. Loker Hydrocarbon Research Institute,Department of Chemistry,University of Southern California,Los Angeles,CA 90089-1661,USA
Abstract:
Keywords:Silicon containing polymer   Heck reaction   photolumincscence.
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