Design of molecules and noncentrosymmetric crystals of 3-(4-nitrophenyl)-2-phenylacrylic acid derivatives |
| |
Authors: | L N Kuleshova V N Khrustalev K Yu Suponitskii M Yu Antipin D V Gusev E S Bobrikova |
| |
Institution: | (1) Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia |
| |
Abstract: | The derivatives of 3-(4-nitrophenyl)-2-phenylacrylic acid are synthesized. It is shown that the chemical modification of this acid results in a change in the symmetry of the supramolecular fragment formed by molecules in the crystal. In turn, this change leads to a change in the crystal symmetry and favors the formation of a noncentrosymmetric crystal structure. The crystal structures of 3-(4-nitrophenyl)-2-phenylacrylic acid (I), 3-(4-nitrophenyl)-2-phenyl-triethyl aminoacrylate (II), and 3-(4-nitrophenyl)-2-phenylacrylic acid (3-methoxy)phenyl ester (III) are investigated by X-ray diffraction. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|