The synthesis,characterization and reactions of a binuclear tetramethylplatinum(IV) complex |
| |
| Authors: | Marym Lashanizadehgan Mehdi Rashidi Janet E. Hux Richard J. Puddephatt Samson S.M. Ling |
| |
| Affiliation: | Department of Chemistry, College of Arts and Sciences, Shiraz University, Shiraz BBBBIran;Department of Chemistry, University of Western Ontario, London N6A 5B7 BBBBCanada |
| |
| Abstract: | Reaction of excess MeLi and MeI with [PtCl2SMe2)2] gives the first binuclear tetramethylplatinum(IV) complex [Pt2Me8(μ-SMe2)2]. The characterization of this complex, and its reactions with donor ligands to give cis-[PtMe4L2] (L2 = Ph2PCH2PPh2, Ph2PCH2CH2PPh2, 2,2′-bipyridyl, 1,10-phenanthroline or L = PMe2Ph, PMePh2) are described. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
