The μ3-cyclopentadienylidene ligand: X-ray structure of [Ru4(CO)5 {P(OMe)3}(μ3-C5H4)2(η-C5H5)2] |
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| Authors: | Neil D Feasey Nigel J Forrow Graeme Hogarth Selby AR Knox Kirsty A Macpherson Michael J Morris A Guy Orpen |
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| Institution: | Department of Inorganic Chemistry, The University, Bristol BS8 1TS, Great Britain |
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| Abstract: | UV irradiation of Ru2(CO)4(η-C5H5)2] yields the tri- and tetra-ruthenium complexes Ru2(CO)4(η-C5H5){η-C5H4Ru(CO)2(η-C5H5)}] and Ru4(CO)6(μ3-C5H4)2(η-C5H5)2]. The μ3-C5H4 ligand in the latter has been characterised through an X-ray diffraction study on Ru4(CO)5{P(OMe)3}(μ3-C5H4)2(η-C5H5)2]. |
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