Infrared,raman and nmr study of (Ch2CH)3Snx compounds (X = Cl,Br, I) |
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| Authors: | E. Vincent L. Verdonck L. Naessens G.P. Van Der K.Elen |
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| Affiliation: | Laboratory for General and Inorganic Chemistry, University of Cent, Krijgslaan 281, B-9000 Cent Belgium |
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| Abstract: | The infrared, Raman and (1H, 13C) NMR spectra of trivinyltin chloride, bromide and iodide have been analyzed and discussed. The vibrational assignment has been confirmed by an approximate normal coordinate analysis. Evidence has been found for a marked influence of the X substituent on the tin-carbon bond due to isovalent rehybridization. Variations in the π electron system of the vinyl group are hardly significant. |
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